Formic acid dehydrogenation over PdNi alloys supported on N-doped carbon: synergistic effect of Pd–Ni alloying on hydrogen release
نویسندگان
چکیده
Among the various Pd1Nix alloys (x = 0.33, 1 and 3) supported on nitrogen-doped carbon, Pd1Ni1/N–C has highest activity for formic acid (HCO2H, FA) dehydrogenation as a result of synergistic interactions between Pd Ni atoms.
منابع مشابه
Efficient PdNi and PdNi@Pd-catalyzed hydrogen generation via formic acid decomposition at room temperature.
Formic acid (FA) holds great potential as a convenient source of hydrogen for sustainable chemical synthesis and renewable energy storage. Herein, the non-noble metal nickel (Ni) exhibits superior promoting effect in improving the catalytic activity of Pd toward high activity and selectivity for FA decomposition at room temperature.
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ژورنال
عنوان ژورنال: Physical Chemistry Chemical Physics
سال: 2021
ISSN: ['1463-9076', '1463-9084']
DOI: https://doi.org/10.1039/d1cp00236h